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Optica, Optical Materials Express, 3(1), p. 379, 2011

DOI: 10.1364/ome.1.000379

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Exciton states of CdTe tetrapod-shaped nanocrystals

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Excitons of CdTe tetrapod-shaped nanocrystals are theoretically analyzed. Individual electron and hole states are calculated by solving one-particle Schrödinger equation by the finite element method with the single-band effective-mass approximation and exciton states are obtained by numerical diagonalization of the configuration interaction Hamiltonian. Spatial symmetries of the exciton states are related to those of the one-particle states by group theory and verified by numerical calculation. It is shown that the lowest exciton state is an optically active A1 exciton. Optical absorption spectra are calculated and compared with available experimental data.