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IOP Publishing, Nanotechnology, 20(21), p. 205602, 2010

DOI: 10.1088/0957-4484/21/20/205602

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Ordered Coalescence of Nanocrystals: A Path to Strong Macroporous Nanoceramics

Journal article published in 2010 by Zhijian Shen, Yan Xiong, Thomas Höche, David Salamon, Zhengyi Fu, Lyubov Belova ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

A versatile approach for integrating two apparently conflicting physical properties, high porosity and high mechanical strength, in polycrystalline bulks is established and demonstrated for the case of alumina ceramics. Macroporous alumina nanoceramics are synthesized by stimulating coalescence-mediated necking, which enables the formation of strong crystallographically coherent necks between adjacent grains. The work places a general emphasis on manipulating crystal growth on the nanoscale and on preparing highly porous polycrystalline bulk ceramics with improved mechanical rigidity.