Published in
Elsevier, Inorganic Chemistry Communications, 10(12), p. 1042-1044
DOI: 10.1016/j.inoche.2009.08.016
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A new synthetic route towards a Ru(III) substituted heteropolytungstate anion
Journal article published in 2009 by
Claire Besson,
Su-Wen Chen,
Richard Villanneau,
Guillaume Izzet,
Anna Proust 
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Abstract
Microwave irradiation of a mixture of K7[PW11O39]·14H2O and [Ru(dmf)6](CF3SO3)3 allowed the straightforward hydrothermal synthesis of the Keggin-type [PW11O39RuIII(OH2)]4− anion. Physical characterizations of the corresponding tetrabutylammonium (TBA) salt are herein described. This study provides a complete set of spectroscopic and electrochemical references for RuIII-incorporating heteropolytungstates.