IOP Publishing, Measurement Science and Technology, 1(18), p. 190-200, 2006
DOI: 10.1088/0957-0233/18/1/024
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The reaction of metal chloride, MCln (where M = Ga, Sb or Sn) and ethyl acetate under atmospheric pressure chemical vapour deposition (APCVD) conditions leads to the production of metal oxide thin films on a variety of gas sensor substrates. Scanning electron microscopy indicated that an island growth mechanism predominated. X-ray photoelectron spectroscopy revealed binding energy shifts similar to previous literature values. Energy dispersive x-ray analysis, wavelength dispersive x-ray analysis and electron probe microanalysis gave coherent elemental compositions indicating that single-phase materials were made, with negligible impurity levels. The films showed little optical reflectance (~10%) and 65–75% total transmission from 400–800 nm. Gas sensing experiments indicated that the APCVD produced films responded best to a reducing gas at 450 °C, whereas the corresponding screen-printed metal oxide sensors were generally more responsive and responded best to a reducing gas at 500 °C.