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Elsevier, Earth and Planetary Science Letters, 1-2(294), p. 131-142

DOI: 10.1016/j.epsl.2010.03.021

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Grain size effects on 230Thxs inventories in opal-rich and carbonate-rich marine sediments

This paper is available in a repository.
This paper is available in a repository.

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Abstract

Excess Thorium-230 (230Thxs) as a constant flux tracer is an essential tool for paleoceanographic studies, but its limitations for flux normalization are still a matter of debate. In regions of rapid sediment accumulation, it has been an open question if 230Thxs-normalized fluxes are biased by particle sorting effects during sediment redistribution. In order to study the sorting effect of sediment transport on 230Thxs, we analyzed the specific activity of 230Thxs in different particle size classes of carbonate-rich sediments from the South East Atlantic, and of opal-rich sediments from the Atlantic sector of the Southern Ocean. At both sites, we compare the 230Thxs distribution in neighboring high vs. low accumulation settings. Two grain-size fractionation methods are explored.We find that the 230Thxs distribution is strongly grain size dependent, and 50–90% of the total 230Thxs inventory is concentrated in fine material smaller than 10µm, which is preferentially deposited at the high accumulation sites. This leads to an overestimation of the focusing factor Ψ, and consequently to an underestimation of the vertical flux rate at such sites. The distribution of authigenic uranium indicates that fine organic-rich material has also been re-deposited from lateral sources. If the particle sorting effect is considered in the flux calculations, it reduces the estimated extent of sediment focusing. In order to assess the maximum effect of particle sorting on Ψ, we present an extreme scenario, in which we assume a lateral sediment supply of only fine material