Published in

American Institute of Physics, The Journal of Chemical Physics, 13(139), p. 134107

DOI: 10.1063/1.4822046

Links

Tools

Export citation

Search in Google Scholar

Heterogeneous nucleation in multi-component vapor on a partially wettable charged conducting particle. I. Formulation of general equations: Electrical surface and line excess quantities

Journal article published in 2013 by M. Noppel, H. Vehkamaki ORCID, P. M. Winkler, M. Kulmala ORCID, P. E. Wagner
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
Green circle
Postprint: archiving allowed
Orange circle
Published version: archiving restricted
Data provided by SHERPA/RoMEO

Abstract

Thermodynamics is applied to formulate general equations for internal energies and grand potential for a system consisting of a dielectric liquid nucleus of a new phase on a charged insoluble conducting sphere within a uniform macroscopic one- or multicomponent mother phase. The currently available model for ion-induced nucleation assumes complete spherical symmetry of the system, implying that the seed ion is immediately surrounded by the condensing liquid from all sides. We take a step further and treat more realistic geometries, where a cap-shaped liquid cluster forms on the surface of the seed particle. To take into account spontaneous polarization of surface layer molecules we introduce the electrical surface and line excess quantities.