Coherent transport of quantum particles in binary superlattices driven by an ac force can realize a kind of quantum walk (QW) that can be referred to as Bloch–Zener QW. In this regime, the particle wavepacket undergoes a sequence of Zener tunnelling events that mimic a discrete QW on a lattice, provided that the impulse of the ac force over one semi-cycle of oscillation is properly adjusted. In the Bloch–Zener QW, the coin states are related to the particle occupation of the two minibands, and thus it does not require any internal degrees of freedom of the particle.