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American Physical Society, Physical Review Letters, 13(94), 2005

DOI: 10.1103/physrevlett.94.137202

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Probing Spin Correlations with Phonons in the Strongly Frustrated MagnetZnCr2O4

Journal article published in 2005 by A. B. Sushkov, O. Tchernyshyov ORCID, W. Ratcliff Ii, S. W. Cheong, H. D. Drew
This paper is available in a repository.
This paper is available in a repository.

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Abstract

The spin-lattice coupling plays an important role in strongly frustrated magnets. In ZnCr2O4, an excellent realization of the Heisenberg antiferromagnet on the pyrochlore network, a lattice distortion relieves the geometrical frustration through a spin-Peierls-like phase transition at T(c)=12.5 K. Conversely, spin correlations strongly influence the elastic properties of a frustrated magnet. By using infrared spectroscopy and published data on magnetic specific heat, we demonstrate that the frequency of an optical phonon triplet in ZnCr2O4 tracks the nearest-neighbor spin correlations above T(c). The splitting of the phonon triplet below T(c) provides a way to measure the spin-Peierls order parameter.