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Elsevier, Journal of Organometallic Chemistry, 9(690), p. 2376-2380

DOI: 10.1016/j.jorganchem.2005.02.014

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Probing delocalisation across highly ethynylated mono and dinuclear Pt(II) tethers containing nitrogroups and organic models as redox active probes: X-ray crystal structure of trans-[Pt(CC–C6H4NO2)2(PPh3)2]

Journal article published in 2005 by Mauro Ravera, Rosaria D’Amato, Annalisa Guerri ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

The electrochemical study on Pt(II) organometallic and organic ethynylated compounds bearing nitro substituents in the phenyl groups has been performed, demonstrating that the presence of severe chemical irreversibility accompanying the electron transfer, preclude an evaluation of the electronic communication between redox active centres. The X-ray structure of the complex trans[Pt(C&3bond; C-C6H4NO2)(2)(PPh3)(2)] is showed. (c) 2005 Elsevier B.V. All rights reserved.