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American Chemical Society, Inorganic Chemistry, 8(51), p. 4423-4425, 2012

DOI: 10.1021/ic3002256

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Porous Double-Walled Metal Triazolate Framework Based upon a Bifunctional Ligand and a Pentanuclear Zinc Cluster Exhibiting Selective CO2Uptake

Journal article published in 2012 by Wen-Yang Gao, Wuming Yan, Rong Cai, Le Meng, Andrea Salas, Xi-Sen Wang, Lukasz Wojtas, Xiaodong Shi, Shengqian Ma ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

The self-assembly of a custom-designed bifunctional ligand featuring both 1,2,3-triazolate and carboxylate donor groups with a pentanuclear zinc cluster generated in situ affords a double-walled metal triazolate framework (MTAF) material, MTAF-1 (Zn(5)(μ(3)-O)(2)(C(9)N(3)H(5)O(2))(5)(H(+))(4)(H(2)O)(17)(C(3)H(7)NO)(10)), which exhibits a surface area of 2300 m(2)/g and demonstrates interesting selective CO(2) uptake performances.