Published in

American Chemical Society, Langmuir, 4(15), p. 1562-1569, 1999

DOI: 10.1021/la9805793

Links

Tools

Export citation

Search in Google Scholar

Direct Measurement of Hydrophobic Forces: A Study of Dissolved Gas, Approach Rate, and Neutron Irradiation

Journal article published in 1999 by V. S. J. Craig ORCID, B. W. Ninham, R. M. Pashley
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
  • Must obtain written permission from Editor
  • Must not violate ACS ethical Guidelines
Orange circle
Postprint: archiving restricted
  • Must obtain written permission from Editor
  • Must not violate ACS ethical Guidelines
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

Theoretical interpretations of the, as yet, poorly understood long-range hydrophobic attraction are briefly reviewed. We report long-range hydrophobic attractive forces between silica surfaces made hydrophobic by adsorption of the cationic surfactants cetyltrimethylammonium bromide and cetylpyridinium chloride onto silica surfaces. The effects of dissolved gas, surface approach velocity, and neutron irradiation on the measured interaction have been studied in order to investigate possible non-electrostatic mechanisms for the long-range hydrophobic attraction. At large separations the presence of dissolved gas, neutron irradiation, and reduced approach velocities are, in each case, found to result in a stronger attraction between the hydrophobic surfaces. These results are consistent with mechanisms related to the metastability of the thin aqueous film separating the approaching hydrophobic surfaces.