Synthesis of aP-Stereogenic PNPtBu,PhRuthenium Pincer Complex and Its Application in Asymmetric Reduction of Ketones
Journal article published in 2015 by
Ismael Arenas,
Omar Boutureira,
M. Isabel Matheu,
Yolanda Díaz,
Sergio Castillón 
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Abstract
A novel P-stereogenic PNPtBu,Ph ruthenium complex has been synthesized and characterized enabling the asymmetric hydrogenation of a wide range of aromatic ketones with excellent catalytic activities (up to 98 % conversion) and good levels of enantiodiscrimination (up to 95 % ee).