The first example of a documented electroforming process dates back to1837 when a layer of electrodeposited copper was found on the surface of a printing plate. Since then, it became a basic manufacturing process to produce delicate metallic components such as nickel thin foils for solar panels, perforated screen-printing cylinders used for fabric and carpet printings, digital recording devices, etc. Recently, electroforming is used for the fabrication of iron-based materials designed for cardiovascular stents. Electroformed iron shows a higher corrosion rate in simulated biological environment; this behaviour is supposed to be influenced by its microstructure which is finer than that of iron produced with traditional techniques. A high corrosion rate can be beneficial for cardiovascular applications: a complete stent dissolution in 12–18 months can effectively prevent both late thrombosis and further treatment of paediatric patients, usually requiring a continuous vessel remodelling. Faster corrosion rate of iron-based material is advantageous for cardiovascular stent application in order to avoid late stent thrombosis and arterial growth mismatch in young patients leading to a secondary revascularization procedure. Electroformed iron has mechanical properties comparable to those of stainless steel (stent reference metal) with the advantage of the total dissolution of the material after the accomplishment of its function: for this reason, this metal can be considered a valid alternative to magnesium-based materials. Nevertheless, electroforming is influenced by parameters such as electrolyte bath composition, current density, pH, temperature, additives, cathode, etc. that have a significant effect on the structure of the produced materials.