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Elsevier, Tetrahedron, 39(71), p. 7144-7153, 2015

DOI: 10.1016/j.tet.2014.11.021

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A convergent, modular access to α-chloro-trifluoromethyl derivatives and to 1,1-difluoroalkenes

Journal article published in 2015 by Pierre Salomon, Wioletta Kosnik ORCID, Samir Z. Zard
This paper is available in a repository.
This paper is available in a repository.

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Abstract

An efficient protocol for the preparation of S-(1-chloro-2,2,2-trifluoroethyl)-O-ethyl xanthate is reported. This reagent serves as a versatile precursor of highly functionalized gem-difluoroalkenes through various inter- and intramolecular radical reactions and subsequent reduction with activated magnesium metal. (C) 2014 Elsevier Ltd. All rights reserved.