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American Chemical Society, Journal of Organic Chemistry, 19(80), p. 9767-9773, 2015

DOI: 10.1021/acs.joc.5b01564

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Pseudo-Multicomponent Reactions of Arynes with N-Aryl Imines

Journal article published in 2015 by Juan-Carlos Castillo, Jairo Quiroga, Rodrigo Abonia, Jean Rodriguez, Yoann Coquerel ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Pseudo-three-component reactions are de- scribed for the conversion of simple N-aryl imines into 1,2- dihydroisoquinoline-type products. The approach relies on a regioselective cascade reaction involving two equivalents of the aryne component iteratively as a dienophile and as an electrophile. Some examples of related, more complex pseudo-four-component cascade processes are also reported.