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Sociedade Brasileira de Química, Química Nova, 5(31)

DOI: 10.1590/s0100-40422008000500011

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Síntese do pigmento cerâmico verde vitória (Ca3Cr2Si3O12) a partir de CaCO3, Cr2O3 e SiO2

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The synthesis of the ceramic pigment Victoria Green (Ca3Cr2Si3O12 ) is described. As raw materials CaCO3, Cr2O3, and SiO2 obtained from rice husk were used. Borax was used as mineralizer. Raw materials were formulated stoichiometrically and calcined from 1000 to 1200 ºC for 180 min. The main phase detected was uvarovite with particle size below 45 mm. The pigments were applied on ceramic tiles and sintered at 1150 ºC for 40 min. The synthesis process showed to be adequate to produce the green pigment, whose characteristics resemble those of a commercial pigment.