Dissemin is shutting down on January 1st, 2025

Published in

American Chemical Society, Macromolecules, 13(31), p. 4301-4308, 1998

DOI: 10.1021/ma971577c

Links

Tools

Export citation

Search in Google Scholar

Synthesis of poly(styrene-dimethylsiloxane) block copolymers: Influence of the phase-separated morphologies on the thermal behaviors

Journal article published in 1998 by David Rosati, Michel-Yves Perrin, Patrick Navard, Valeria Harabagiu, Mariana Pinteala ORCID, Bogdan C. Simionescu
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

Full text: Unavailable

Green circle
Preprint: archiving allowed
  • Must obtain written permission from Editor
  • Must not violate ACS ethical Guidelines
Upload
Orange circle
Postprint: archiving restricted
  • Must obtain written permission from Editor
  • Must not violate ACS ethical Guidelines
Upload
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

Five polystyrene-poly(dimethylsiloxane) di- and triblock copolymers were prepared by two different methods, a classical anionic polymerization and a cationic polymerization of styrene in the presence of a new macromolecular initiator. Spherical, cylindrical, and lamellar phase-separated morphologies were identified. Their sizes were measured by transmission electron microscopy (TEM) on films obtained from bulk and solvent-cast samples. DSC and TEM show that the phase-separated morphologies are strongly segregated with no long range ordering. The specific microphase surface area, obtained by TEM, is strongly correlated with the broadening of the polystyrene glass transition.