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American Physical Society, Physical Review Letters, 20(105)

DOI: 10.1103/physrevlett.105.203201

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Kinetics and Dynamics of theS(D21)+H2→SH+HReaction at Very Low Temperatures and Collision Energies

This paper is available in a repository.
This paper is available in a repository.

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Abstract

We report combined studies on the prototypical S(1D2) + H2 insertion reaction. Kinetics and crossed-beam experiments are performed in experimental conditions approaching the cold energy regime, yielding absolute rate coefficients down to 5.8 K and relative integral cross sections to collision energies as low as 0.68 meV. They are supported by quantum calculations on a potential energy surface treating long-range interactions accurately. All results are consistent and the excitation function behavior is explained in terms of the cumulative contribution of various partial waves.