Published in

American Institute of Physics, The Journal of Chemical Physics, 12(131), p. 124504

DOI: 10.1063/1.3197851

Links

Tools

Export citation

Search in Google Scholar

The low frequency phonons dynamics in supercooled LiCl, 6H2O

This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
Green circle
Postprint: archiving allowed
Orange circle
Published version: archiving restricted
Data provided by SHERPA/RoMEO

Abstract

We report the results of a series of ultrasound, Brillouin scattering, and optical heterodyne detected transient grating experiments performed on a LiCl, 6H2O solution from room temperature down to the vicinity of its liquid-glass transition, Tg ∼ 138 K. Down to T ∼ 215 K, the supercooled liquid has a behavior similar to what is expected for supercooled water: its zero frequency sound velocity, C0, continuously decreases while the corresponding infinite frequency velocity, C∞, sharply increases, reflecting the increasing importance of H bonding when temperature is lowered. Below 215 K, specific aspects of the solution, presumably related to the role of the Li+ and Cl− ions, modify the thermal behavior of C0, while a β relaxation process also appears and couples to the sound propagation. The origin of those two effects is briefly discussed.