Published in

Taylor and Francis Group, High Pressure Research, 1(30), p. 151-158, 2010

DOI: 10.1080/08957950903554576

Links

Tools

Export citation

Search in Google Scholar

Kinetics of the isostructural γ to α transition in cerium investigated by ultrasonics

Distributing this paper is prohibited by the publisher
Distributing this paper is prohibited by the publisher

Full text: Unavailable

Red circle
Preprint: archiving forbidden
Orange circle
Postprint: archiving restricted
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

We performed ultrasonic pulse echo measurements on high-purity polycrystalline cerium across the isostructural γ to α-fcc-to-fcc transition, up to 13 kbar and then back down to 0.3 kbar. Our results confirm the anomalous decrease of the longitudinal sound velocity in the γ -phase approaching the transition, a significant hysteresis loop, and definitively highlight the strong difference in the long wavelength limit of the lattice dynamics of the γ and α phases. We have also studied the kinetics of the transition, which is well described by an Arrhenius behavior, with an activation volume of 10 cm3/mol.