Published in

Elsevier, Diamond and Related Materials, (37), p. 92-96

DOI: 10.1016/j.diamond.2013.05.001

Links

Tools

Export citation

Search in Google Scholar

Long-term H-release of hard and intermediate between hard and soft amorphous carbon evidenced by in situ Raman microscopy under isothermal heating

This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
Red circle
Postprint: archiving forbidden
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

We study the kinetics of the H release from plasma-deposited hydrogenated amorphous carbon films under isothermal heating at 450, 500 and 600 degrees C for long times up to several days using in situ Raman microscopy. Four Raman parameters are analyzed. They allow the identification of different processes such as the carbon network reorganization and the H release from sp(3) or sp(2) carbon atoms and the corresponding timescales. Carbon reorganization with aromatization and loss of sp(3) hybridization occurs first in 100 min at 500 degrees C. The final organization is similar at all investigated temperatures. Full H release from sp(3) carbon occurs on a longer timescale of about 10 h while H release from sp(2) carbon atoms is only partial, even after several days. All these processes occur more rapidly with higher initial H content, in agreement with what is known about the stability of these types of films. A quantitative analysis of these kinetics studies gives valuable information about the microscopic processes at the origin of the H release through the determination of activation energies.