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Royal Society of Chemistry, Chemical Science, 2(6), p. 993-1003, 2015

DOI: 10.1039/c4sc02705a

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Electron localization in a mixed-valence diniobium benzene complex

Journal article published in 2015 by Thomas L. Gianetti, Gregory Nocton, Stefan G. Minasian, Nikolas Kaltsoyannis ORCID, A. L. David Kilcoyne, Al David Kilcoyne, Stosh A. Kozimor, David K. Shuh, Tolek Tyliszczak, Robert G. Bergman, John Arnold ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

One electron oxidation of a neutral diniobium benzene complex leads to a mixed-valence species. Single crystal X-ray diffraction, EPR, L3,2-edge XANES, and DFT indicate that the unpaired electron is localized on one metal center.