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American Chemical Society, Journal of Organic Chemistry, 6(70), p. 2322-2324, 2005

DOI: 10.1021/jo047910+

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Heterocyclic rearrangements in constrained media. A zeolite-directed photorearrangement of 1,2,4-oxadiazoles

Journal article published in 2005 by Silvestre Buscemi, Andrea Pace ORCID, Nicolo' Vivona
This paper is available in a repository.
This paper is available in a repository.

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Abstract

[reaction: see text] The first intrazeolite-photoinduced rearrangement of a five-membered heterocycle is reported. A completely different behavior compared to solution irradiations has been observed. The zeolite's role in directing the photoreaction of 3-phenyl-1,2,4-oxadiazoles toward the formation of the corresponding 1,3,4-oxadiazoles in a ring contraction-ringexpansion route is discussed.