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American Institute of Physics, Journal of Applied Physics, 5(105), p. 054106

DOI: 10.1063/1.3087611

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Ferroelectric Phase Transitions in Three-Component Short-Period Superlattices Studied by Ultraviolet Raman Spectroscopy

Journal article published in 2009 by Dmitri A. Tenne, Ho Nyung Lee, Ram S. Katiyar, Xx X. Xi ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Vibrational spectra of three-component BaTiO 3/ SrTiO 3/ CaTiO 3 short-period superlattices grown by pulsed laser deposition with atomic-layer control have been investigated by ultraviolet Raman spectroscopy. Monitoring the intensity of the first-order phonon peaks in Raman spectra as a function of temperature allowed the determination of the ferroelectric phase transition temperature Tc . Raman spectra indicate that all superlattices remain in the tetragonal ferroelectric phase with out-of-plane polarization in the entire temperature range below Tc . The dependence of Tc on the relative thicknesses of ferroelectric ( BaTiO 3) to nonferroelectric materials ( SrTiO 3 and CaTiO 3 ) has been studied. The highest Tc was found in superlattices having the largest relative amount of BaTiO 3 , provided that the superlattice maintains its coherency with the substrate. Strain relaxation leads to a significant decrease in the ferroelectric phase transition temperature.