American Institute of Physics, Journal of Applied Physics, 5(105), p. 054106
DOI: 10.1063/1.3087611
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Vibrational spectra of three-component BaTiO 3/ SrTiO 3/ CaTiO 3 short-period superlattices grown by pulsed laser deposition with atomic-layer control have been investigated by ultraviolet Raman spectroscopy. Monitoring the intensity of the first-order phonon peaks in Raman spectra as a function of temperature allowed the determination of the ferroelectric phase transition temperature Tc . Raman spectra indicate that all superlattices remain in the tetragonal ferroelectric phase with out-of-plane polarization in the entire temperature range below Tc . The dependence of Tc on the relative thicknesses of ferroelectric ( BaTiO 3) to nonferroelectric materials ( SrTiO 3 and CaTiO 3 ) has been studied. The highest Tc was found in superlattices having the largest relative amount of BaTiO 3 , provided that the superlattice maintains its coherency with the substrate. Strain relaxation leads to a significant decrease in the ferroelectric phase transition temperature.