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American Institute of Physics, Journal of Applied Physics, 7(109), p. 07E304

DOI: 10.1063/1.3535544

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Magnetic phase transition and Mossbauer spectroscopy of ErNi2Mnx compounds

Journal article published in 2011 by J. L. Wang ORCID, S. J. Campbell, R. Zeng, S. X. Dou, S. J. Kennedy
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Investigation of ErNi 2 Mn x with 0.90 ≤ x ≤ 1.10 indicates that the MgCu 2 -type structure (with space group Fd-3m) is formed within x = 0.97-1.10. Curie temperature T C  = 50 K of ErNi2Mn is significantly higher than those of the corresponding ErNi 2 (T C  = 7 K) and ErMn 2 (T C  = 15 K) compounds. Detailed analyses of DC magnetization data demonstrate that the magnetic phase transition at the Curie temperature is second order. The magnetic entropy change around T C has been found to be 4.8 J/kg K for a magnetic field change of 0 to 5 T with its relative cooling power ∼283 J/kg. 57Fe Mössbauer spectra below T C have been fitted with three sub-spectra representing three inequivalent local magnetic environments while the paramagnetic spectra are fitted using two sub-spectra for two inequivalent crystal sites (8a and 16d), which supports the conclusion based on Rietveld refinement that Mn atoms occupy at both 8a and 16d sites.