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Wiley, Angewandte Chemie International Edition, 17(50), p. 4007-4011, 2011

DOI: 10.1002/anie.201100306

Wiley, Angewandte Chemie, 17(123), p. 4093-4097, 2011

DOI: 10.1002/ange.201100306

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A Spectroscopic Investigation of Magnetic Exchange Between Highly Anisotropic Spin Centers

Journal article published in 2011 by Angelika B. Boeer, Anne-Laure Barra, Liviu F. Chibotaru, David Collison, Eric J. L. McInnes, Richard A. Mole, Giovanna G. Simeoni, Grigore A. Timco, Liviu Ungur ORCID, Tobias Unruh, Richard E. P. Winpenny
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Abstract

Structurally similar, magnetically diverse: The exchange and Zeeman parameters of two dimetallic, six-coordinate cobalt(II) compounds—i.e., with orbitally degenerate metal ions—have been determined by a combination of high-resolution EPR and INS spectroscopies, together with ab intio calculations. It is suggested that the correlation between the local crystal field about the CoII centers and the superexchange pathway controls the magnetic interaction. © 2011, Wiley-Blackwell. The definitive version is available at www3.interscience.wiley.com