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Wiley, Angewandte Chemie International Edition, 36(49), p. 6315-6318, 2010

DOI: 10.1002/anie.201003177

Wiley, Angewandte Chemie, 36(122), p. 6459-6462, 2010

DOI: 10.1002/ange.201003177

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Reduction of a Chelating Bis(NHC) Palladium(II) Complex to [{μ-bis(NHC)}2Pd2H]+: A Terminal Hydride in a Binuclear Palladium(I) Species Formed under Catalytically Relevant Conditions

Journal article published in 2010 by Peter D. W. Boyd, Alison J. Edwards, Michael G. Gardiner ORCID, Curtis C. Ho ORCID, Marie-Hélène Lemée-Cailleau, David S. McGuinness, Anung Riapanitra, Jonathan W. Steed, Damien N. Stringer, Brian F. Yates
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The first palladium(I) N-heterocyclic carbene complex has been isolated in high yield by the base-assisted reduction of a palladium(II) precursor. The location of the unique terminal hydride (see picture; PdI cyan, H white, N blue) was established by neutron crystal structure determination, and the solution fluxional behavior of the complex was explored. © 2010, Wiley-VCH Verlag Berlin