Published in

American Physical Society, Physical review B, 24(78), 2008

DOI: 10.1103/physrevb.78.245201

Links

Tools

Export citation

Search in Google Scholar

Distance dependence of excitation energy transfer between spacer-separated conjugated polymer films

Journal article published in 2008 by Paul E. Shaw, Arvydas Ruseckas ORCID, Ifor D. W. Samuel ORCID
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
Green circle
Postprint: archiving allowed
Green circle
Published version: archiving allowed
Data provided by SHERPA/RoMEO

Abstract

We report a systematic study of the scaling with distance of electronic energy transfer between thin films of conjugated polymers separated by a silica spacer. The energy-transfer kinetics were obtained directly from time-resolved photoluminescence measurements and show a 1/ z3 distance dependence of the transfer rate between the excited donor and the acceptor film for z≥8 nm. This is consistent with Förster theory; but at shorter separations the energy transfer is slower than predicted and can be explained by the breakdown of the point-dipole approximation at z∼5 nm. The results are relevant for organic photovoltaics and light-emitting devices, where energy transfer can provide a means of increasing performance.