Toward the Total Synthesis of Haliclonin A: Construction of a Tricyclic Substructure
Journal article published in 2012 by
Shi-Peng Luo,
黄培强,
Lian-Dong Guo,
Long-Hui Gao,
Shuang Li,
Pei-Qiang Huang 
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Abstract
Three keys to success: A concise method for the construction of a tricyclic substructure (2) of haliclonin A (1) in racemic form is described (see figure). This synthesis features a new Pd-mediated chemoselective carbonyl-enone coupling reaction, an organocatalytic reaction, and a ring-closing metathesis reaction for the construction of the macrocyclic ring as key steps.