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Elsevier, Chemical Physics Letters, 4-6(463), p. 378-382

DOI: 10.1016/j.cplett.2008.08.082

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New Features in the dynamics of a ferroin-catalyzed Belousov-Zhabotinsky reaction induced by a zwitterionic surfactant

This paper is available in a repository.
This paper is available in a repository.

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Abstract

Interactions between reaction-diffusion systems and aggregated host environments are a subject of widespread interest. In this work, the behavior of the Belousov-Zhabotinsky reaction was investigated in a micellar environment formed by the zwitterionic surfactant N-tetradecyl-N,N-dimethylamine oxide (C14DMAO). The appearance of an induction period with a threshold-like dependence upon the surfactant concentration, was detected at [C14DMAO]�=�5.0ï¿½× 10-3�mol�dm-3. These new features were explained in terms of the segregation ability typical of the amphiphilic self-assembling systems. Numerical simulations were also performed to confirm the proposed mechanism.