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Self-assembled Co(II) molecular squares incorporating the bridging ligand 4,7-phenanthrolino-5,6:5 ',6 '-pyrazine

Journal article published in 2011 by Feng Li, Jack K. Clegg, Deanna M. D'Alessandro, Laurence Goux-Capes, Natasha F. Sciortino, Tony D. Keene ORCID, Cameron J. Kepert
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

Three high-spin tetranuclear cobalt(ii) complexes have been prepared with the bridging ligand 4,7-phenanthrolino-5,6:5′,6′-pyrazine (ppz) through metal-ion directed self-assembly. The complexes differ by the incorporation of three different coordinating anions: chloride, thiocyanide and selenocyanide. The physical properties of these complexes have been investigated in detail.