Published in

American Chemical Society, Langmuir, 17(25), p. 9931-9937, 2009

DOI: 10.1021/la901099g

Links

Tools

Export citation

Search in Google Scholar

Ion Specific Electrolyte Effects on Thin Film Drainage in Nonaqueous Solvents Propylene Carbonate and Formamide

This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
  • Must obtain written permission from Editor
  • Must not violate ACS ethical Guidelines
Orange circle
Postprint: archiving restricted
  • Must obtain written permission from Editor
  • Must not violate ACS ethical Guidelines
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

Electrolytes have been found to stabilize thin films in nonaqueous solvents propylene carbonate and formamide, in the absence of surfactant. The thin film balance microinterferometry technique has been used to measure film lifetimes, drainage kinetics, and rupture thicknesses for thin films between air-nonaqueous solution interfaces. Electrolytes that were previously found to inhibit bubble coalescence in bulk bubble column measurements also increase the lifetimes of individual thin films across it similar concentration range (from 0 to 0.3 M). We report that increasing the concentration of inhibiting electrolyte stabilizes the thin liquid film in two ways: the rate of film drainage decreases, and the film reaches a lower thickness before rupturing. In contrast, non-inhibiting electrolyte shows little to no effect on film stability. We have here demonstrated that both drainage and rupture processes are affected by the addition of electrolyte and the effect on the thin film is thus ion specific.