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Published in

American Institute of Physics, Applied Physics Letters, 8(107), p. 081603

DOI: 10.1063/1.4929696

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Degenerate Mobilities in Phase Field Models are Insufficient to Capture Surface Diffusion

Journal article published in 2015 by Alpha Aa Lee, Andreas Münch ORCID, Endre Süli ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Phase field models frequently provide insight to phase transitions, and are robust numerical tools to solve free boundary problems corresponding to the motion of interfaces. A body of prior literature suggests that interface motion via surface diffusion is the long-time, sharp interface limit of microscopic phase field models such as the Cahn-Hilliard equation with a degenerate mobility function. Contrary to this conventional wisdom, we show that the long-time behaviour of degenerate Cahn-Hilliard equation with a polynomial free energy undergoes coarsening, reflecting the presence of bulk diffusion, rather than pure surface diffusion. This reveals an important limitation of phase field models that are frequently used to model surface diffusion.