In this work, we designed and fabricated a novel one-dimensional CdSe/CdS@TiO2 core-shell nanotube array for quantum dots co-sensitized solar cells (QDSSCs) application. The three-component core-shell nanotube array structure was formed cascade by coating CdS nanoparticles with a successive ionic layer adsorption and reaction process and a thin CdSe layer by chemical bath deposition onto the vertical TiO2 nanotube arrays (TNAs), which enhanced the optical absorption in the visible region and presented an stepwise band-edge level structure to improve the charge separation. Under optimum conditions, the CdS/CdSe co-sensitized QDSSC demonstrated a power conversion efficiency (PCE) of 2.40% under 100 mW/cm(2) illumination of simulate sunlight. Furthermore, an improved QDSSC with a PCE up to 2.74% was obtained by sealed annealing of TNAs, due to the transformation of thin and smooth nanotube to thick and rough particle nanotube. (C) 2012 Elsevier Ltd. All rights reserved. ; National Natural Science Foundation of China [51072170, 21021002]; National High Technology Research and Development Program of China [2009AA03Z327]; National Basic Research Program of China [2012CB932900]; Alexander von Humboldt (AvH) Foundation of Germany