Published in

American Chemical Society, Journal of Physical Chemistry C, 32(112), p. 12515-12523, 2008

DOI: 10.1021/jp801985h

Links

Tools

Export citation

Search in Google Scholar

Structure of tetrakis(melaminium) bis(dihydrogenphosphate) monohydrogenphosphate trihydrate from X-ray powder diffraction and solid-state NMR spectroscopy

Journal article published in 2008 by Vladimir Brodski, René Peschar, Henk Schenk, Andreas Brinkmann ORCID, Ernst R. H. van Eck, E. R. H. van Eck, Arno P. M. Kentgens
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
  • Must obtain written permission from Editor
  • Must not violate ACS ethical Guidelines
Upload
Orange circle
Postprint: archiving restricted
  • Must obtain written permission from Editor
  • Must not violate ACS ethical Guidelines
Upload
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

The crystal structure of the melamine phosphate salt tetrakis(melaminium) bis(dihydrogenphosphate) monohydrogenphosphate trihydrate with as much as ten independent moieties in the unit cell was determined by a direct-space global optimization technique from X-ray powder diffraction data using additional geometry constraints obtained by 31P double-quantum solid-state NMR spectroscopy. The structure analysis of the compound and its comparison with other melamine phosphates reveals the packing and bonding characteristics that are important for melamine-phosphate salts with a melamine-to-phosphor ratio larger than one, which are promising environmental-friendly flame retardants.