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American Physical Society, Physical Review B (Condensed Matter), 8(63), 2001

DOI: 10.1103/physrevb.63.085108

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Tight-binding approach to time-dependent density-functional response theory

This paper is available in a repository.
This paper is available in a repository.

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Abstract

In this paper we propose an extension of the self-consistent charge-density-functional tight-binding (SCC-DFTB) method [M. Elstner et al., Phys. Rev. B 58, 7260 (1998)], which allows the calculation of the optical properties of finite systems within time-dependent density-functional response theory (TD-DFRT). For a test set of small organic molecules low-lying singlet excitation energies are computed in good agreement with first-principles and experimental results. The overall computational cost of this parameter-free method is very low and thus it allows us to examine large systems: we report successful applications to C60 and the polyacene series.