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Wiley, Chinese Journal of Chemistry, 7(29), p. 1312-1318, 2011

DOI: 10.1002/cjoc.201180248

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Enantioselective Synthesis of Glutarimide Alkaloids Cordiarimides A, B, Crotonimides A, B, and Julocrotine

Journal article published in 2011 by Teng Bo, 黄培强, Jianfeng Zheng, Huiying Huang, Peiqiang Huang ORCID
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

Five glutarimide alkaloids cordiarimide A (5), cordiarimide B (6), crotonimide A (3), crotonimide B (4), and julocrotine (2) have been synthesized starting from Boc-L-glutamine (7). The benzylic alcohol chiral centre of cordiarimides B (6) has been established in 6 : 1 diastereoselectivity by catalytic asymmetric hydrogenation using Zhou's catalytic system Pd(CF(3)CO(2))(2)/(R,R)-Me-DuPhos. ; National Natural Science Foundation of China[20832005]; National Basic Research Program (973 Program) of China[2010CB833200]