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Elsevier, Tetrahedron, 10(63), p. 2148-2152, 2007

DOI: 10.1016/j.tet.2006.12.092

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Expeditious biomimetically-inspired approaches to racemic homocitric acid lactone and per-homocitrate

Journal article published in 2007 by 黄培强, 张洪奎, 周朝晖, Hong-Bin Chen, Ling-Yan Chen, Pei-Qiang Huang ORCID, Hong-Kui Zhang, Zhao-Hui Zhou, Khi-Rui Tsai
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Two concise and flexible biomimetically-inspired approaches to homocitric acid lactone (3) and its higher homolog, triethyl per-homocitrate (12), are presented herein. The key steps include an efficient indium metal-mediated allylation-oxidative cleavage procedure and a one-step ethoxycarbonylmethylation of alpha-oxo-diesters. (c) 2006 Published by Elsevier Ltd.