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American Chemical Society, Journal of the American Chemical Society, 49(125), p. 14972-14973, 2003

DOI: 10.1021/ja036515i

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Self-Assembled Nanotubes that Reversibly Bind Acetic Acid Guests

Journal article published in 2003 by Linda S. Shimizu, Andrew D. Hughes, Mark D. Smith, Matthew J. Davis, B. Paul Zhang, Hans-Conrad zur Loye ORCID, Ken D. Shimizu
Distributing this paper is prohibited by the publisher
Distributing this paper is prohibited by the publisher

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Abstract

A large bis-urea macrocycle was synthesized and assembled into columnar nanotubes containing a sizable cavity. This purely organic nanotube is held together primarily by hydrogen bonding and yet shows remarkable thermal stability up to 180 °C in the presence and absence of acetic acid guest. This enables the nanotube to be used as reusable organic zeolite.