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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 8(61), p. m1531-m1533, 2005

DOI: 10.1107/s1600536805021501

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Tris(ethylenediamine)cobalt(III) nonaiododibismuthate

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The asymmetric unit of the title compound, [Co(C2H8N2)3][Bi2I9], crystallizes in the orthorhombic space group Cmc21. The asymmetric unit contains half of a [Co(en)3]3+ cation (en is ethylenediamine) and half of a [Bi2I9]3- anion. Both species are located on mirror planes, requiring the [Co(en)3]3+ cation to be present as a statistically disordered mixture of both enantiomeric forms. Crystals were grown solvothermally from an ethanol-water solvent mixture using rac-[Co(en)3]I3 and bismuth triiodide as starting materials. The compound is a rare example of a mixed-metal halobismuthate material.