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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 1(61), p. i3-i5, 2004

DOI: 10.1107/s1600536804031836

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Sm2NaIrO6, a monoclinically distorted double perovskite

Journal article published in 2004 by Samuel J. Mugavero Iii, Irina V. Puzdrjakova, Mark D. Smith, Hans-Conrad zur Loye ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Single crystals of the lanthanide-containing iridate, disamarium sodium iridium hexaoxide, Sm2NaIrO6, were prepared via high-temperature flux growth and structurally characterized by single-crystal X-ray diffraction. The compound crystallizes in the monoclinic space group P21/n and is a double perovskite, consisting of a 1:1 ordered rock-salt-type lattice of corner-shared NaO6 and IrO6 distorted octahedra. Samarium occupies the eightfold coordination site generated by the connectivity of the octahedra.