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Elsevier, Chemical Physics Letters, 1-3(515), p. 194-196

DOI: 10.1016/j.cplett.2011.08.096

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Transient absorption spectroscopy detection of sensitized delayed fluorescence in chiral benzophenone/naphthalene systems

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This paper is available in a repository.

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Abstract

Transient absorption spectroscopy has proven to be a powerful tool to investigate the formation and decay of excited singlet states upon triplet–triplet annihilation, following T–T energy transfer from a selectively excited sensitizer. Thus, upon selective excitation of benzophenone (BZP) by laser flash photolysis (LFP) at λ = 355 nm in the presence of naphthalene (NPT), a negative band centered at 340 nm has been detected, with growth and decay in the microsecond timescale. It has been assigned to the P-type NPT delayed-fluorescence. In the case of chiral BZP/NPT systems, stereodifferentiation has been observed in the kinetics of the involved photophysical processes ; MICINN CTQ2010-14882 ; Bonancía Roca, P.; Jiménez Molero, MC.; Miranda Alonso, MÁ. (2011). Transient absorption spectroscopy detection of sensitized delayed fluorescence in chiral benzophenone/naphthalene systems. Chemical Physics Letters. 515(1-3):194-196. doi:10.1016/j.cplett.2011.08.096. ; Senia ; 194 ; 196 ; 515 ; 1-3