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American Chemical Society, Organometallics, 6(26), p. 1299-1302, 2007

DOI: 10.1021/om061143i

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Buckling under Strain: Relief of Steric Pressure Occurs Differently for Samarium(III) Porphyrinogen Complexes of the π-Bound Auxiliary Ligands Cyclopentadienyl and Cyclooctatetraenediyl

Journal article published in 2007 by Alistair S. P. Frey, Michael G. Gardiner ORCID, Damien N. Stringer, Brian F. Yates, Adrian V. George, Paul Jensen, Peter Turner
This paper is available in a repository.
This paper is available in a repository.

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Abstract

The most adhered to strategy in inorganic chemistry for stabilizing reactive functionalities, achieving reaction selectivities, and accessing novel structural motifs is the use of hindered “nonparticipative ligands” to afford protection and/or force unusual/desired behavior.