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Wiley, Macromolecular Rapid Communications, 9(28), p. 1024-1028, 2007

DOI: 10.1002/marc.200700037

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Chiral polymer helices with shape identical to previously reported helical calcium carbonate morphologies

Journal article published in 2007 by Fabian Glaab, Matthias Kellermeier, Werner Kunz ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Helixes with highly ordered substructures were found sporadically during pptn. of self-assembled SiO2-Ba carbonate biomorphs. Identical morphologies are already known and cited in the literature as helical calcite structures, formed by the influence of chiral phosphoserine copolypeptides. Yamamoto et al. claim that the handedness of the helixes can be tuned by the chirality of the amino acids in the phosphoserine copolypeptides. Optical and SEM, energy-dispersive x-ray anal., Tg, as well as proton and C NMR were performed on selected twisted ribbons, proving that these helical superstructures, in shape identical to the helical calcite morphologies reported by Yamamoto et al., do not consist of inorg. material but of an org. polymer, representing plastic abrasion caused by scratching glass pipets along plastic surfaces.