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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 12(66), p. o3243-o3244, 2010

DOI: 10.1107/s1600536810047604

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Trimethyl 2,2′,2′′-[1,3,5-triazine-2,4,6-tri­yltris­(aza­nedi­yl)]triacetate

Journal article published in 2010 by Sérgio M. F. Vilela, Verónica de Zea Bermudez, Filipe A. Almeida Paz, João P. C. Tomé ORCID, Verónica de Zea Bermudez, José A. S. Cavaleiro ORCID, João Rocha ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The title compound, C(12)H(18)N(6)O(6), was synthesized via nucleophilic substitution by reacting 2,4,6-trichloro-1,3,5-triazine with glycine methyl ester hydro-chloride in reflux (dried toluene) under anhydrous atmosphere. Individual mol-ecules self-assemble via strong N-H⋯O hydrogen bonds into supra-molecular double tapes running parallel to the [010] crystallographic direction. The close packing of supra-molecular tapes is mediated by geometrical reasons in tandem with a number of weaker N-H⋯O and C-H⋯N hydrogen-bonding inter-actions.