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Wiley, Angewandte Chemie International Edition, 22(50), p. 5200-5203, 2011

DOI: 10.1002/anie.201101095

Wiley, Angewandte Chemie, 22(123), p. 5306-5309, 2011

DOI: 10.1002/ange.201101095

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Mesoporous Zeolite-Supported Ruthenium Nanoparticles as Highly Selective Fischer-Tropsch Catalysts for the Production of C(5)-C(11) Isoparaffins

Journal article published in 2011 by Jincan Kang, 张庆红, 王野, Kang Cheng, Lei Zhang, Qinghong Zhang, Jiansheng（Yantai Wanhua Polyurethanes Co Ltd） Ding, Weiqi（Yantai Wanhua Polyurethanes Co Ltd） Hua, Yinchuan（Yantai Wanhua Polyurethanes Co Ltd） Lou, Qingge Zhai, Ye Wang ORCID
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Abstract

A highly selective catalyst based on mesoporous zeolites for the production of C5-C11 isoparaffins from syngas has been developed. The selectivity to C5-C11 hydrocarbons over Ru/meso-ZSM-5 reaches about 80 % with a ratio of isoparaffins to n-paraffins of 2.7:1. The mesoporous structure and the unique acidity of meso-ZSM-5 play key roles in tuning the product selectivity by controlling the secondary hydrocracking reactions.