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Wiley, Angewandte Chemie International Edition, 10(51), p. 2438-2442, 2012

DOI: 10.1002/anie.201104071

Wiley, Angewandte Chemie, 10(124), p. 2488-2492, 2012

DOI: 10.1002/ange.201104071

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Transformation of Methane to Propylene: A Two-Step Reaction Route Catalyzed by Modified CeO2 Nanocrystals and Zeolites

Journal article published in 2012 by Jieli He, 王野, 张庆红, Ting Xu, Zhihui Wang, Qinghong Zhang, Weiping Deng, Ye Wang ORCID
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This paper is available in a repository.

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Abstract

Propylene from methane: The transformation of methane to propylene has been realized in a two-step route via CH(3) Cl or CH(3) Br. CeO(2) serves as an efficient and stable catalyst for the oxidative chlorination and bromination of methane to CH(3) Cl and CH(3) Br. In the second step, a modified zeolite is highly a selective and stable catalyst for the conversion of CH(3) Cl or CH(3) Br into propylene.