Published in

MDPI, Materials, 4(8), p. 1652-1665, 2015

DOI: 10.3390/ma8041652

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Tuning the pore geometry of ordered mesoporous carbons for enhanced adsorption of bisphenol-A

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Mesoporous carbons were synthesized via both soft and hard template methods and compared to a commercial powder activated carbon (PAC) for the adsorption ability of bisphenol-A (BPA) from an aqueous solution. The commercial PAC had a BET-surface of 1027 m 2 /g with fine pores of 3 nm and less. The hard templated carbon (CMK-3) material had an even higher BET-surface of 1420 m 2 /g with an average pore size of 4 nm. The soft templated carbon (SMC) reached a BET-surface of 476 m 2 /g and a pore size of 7 nm. The maximum observed adsorption capacity (qmax) of CMK-3 was the highest with 474 mg/g, compared to 290 mg/g for PAC and 154 mg/g for SMC. The difference in adsorption OPEN ACCESS Materials 2015, 8 1653 capacities was attributed to the specific surface area and hydrophobicity of the adsorbent. The microporous PAC showed the slowest adsorption, while the ordered mesopores of SMC and CMK-3 enhanced the BPA diffusion into the adsorbent. This difference in adsorption kinetics is caused by the increase in pore diameter. However, CMK-3 with an open geometry consisting of interlinked nanorods allows for even faster intraparticle diffusion.