Elsevier, Journal of Electroanalytical Chemistry, 1-2(646), p. 107-113
DOI: 10.1016/j.jelechem.2010.03.020
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The voltammetric response of a bipolar cell, formed by making electrical connection between two half-cells under overall potentiostatic control, is described. Experimental data obtained with reversible redox couples are compared with numerical simulations of the corresponding two-phase transport problem, where charge transfer may be limited by the transport of either, or both, of the redox-active couples. Preliminary experiments on the extension of the system to more complex electron transfer processes, specifically metal deposition, are also described.