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Wiley, Chirality, 1(13), p. 2-6, 2000

DOI: 10.1002/1520-636x(2001)13:1<2::aid-chir2>3.0.co;2-u

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Molecular polarization and molecular chiralization: The first example of a chiralized xenon atom

Journal article published in 2000 by Kristin Bartik ORCID, Michel Luhmer, André Collet, A. Jacques Reisse
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

In this article we focus on the interaction between a chiral molecule and a single achiral molecule or an ensemble of achiral molecules. The desymmetrization of the achiral molecules resulting from this interaction is described as ldquochiralization.rdquo By analogy with electric polarization, we factorize chiralization into three factors, i.e. orientation, atomic, and electronic terms. Chiralization depends on the dipolar polarizability of the chiralized molecule but also on polarizabilities of higher order. The experimental part of this work is devoted to the electronic chiralization of a xenon atom and its observation by 129Xe NMR spectroscopy. ; info:eu-repo/semantics/published